OPTICAL-ACTIVITY OF CHIRAL DENDRITIC SURFACES

被引：108

作者：

JANSEN, JFGA

PEERLINGS, HWI

DEBRABANDERVANDENBERG, EMM

MEIJER, EW

机构：

[1] EINDHOVEN UNIV TECHNOL,ORGAN CHEM LAB,5600 MB EINDHOVEN,NETHERLANDS

[2] DSM RES BV,6160 MD GELEEN,NETHERLANDS

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 11期

关键词：

CHIRALITY; CHIROPTICAL STUDIES; CIRCULAR DICHROISM; DENDRIMERS; STEREOCHEMISTRY;

D O I：

10.1002/anie.199512061

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The optical rotation of poly(propylene imine) dendrimers with 64 identical enantiomerically pure amino acid end groups tends to zero. This remarkable behavior results from the packing of the end groups in the highly dense, multiply hydrogenbonded surface, which gives rise to different frozen‐in conformations, leading to an internal compensation of optical activity. Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1206 / 1209

页数：4

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