SOLVENT EFFECTS IN NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY OF MONOSACCHARIDES .I. BENZENE-INDUCED SHIFTS OF ACETYLATED MONOSACCHARIDES

被引:16
作者
FREEMANTLE, MH
OVEREND, WG
机构
[1] Chemistry Department, Birkbeck College (University of London), London
来源
JOURNAL OF THE CHEMICAL SOCIETY B-PHYSICAL ORGANIC | 1969年 / 05期
关键词
D O I
10.1039/j29690000547
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
An exploratory study is reported of the benzene-induced shifts in the n.m.r. spectra of a range of acetylated monosaccharides. The solvent-induced shifts have been shown to be configurationally dependent and certain trends can be traced. The new results are discussed in terms of a model involving ' benzene-solute association'.
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页码:547 / +
页数:1
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