ENZYMATIC REGIOSELECTIVE ALKOXYCARBONYLATION OF HEXOSES AND PENTOSES WITH CARBONATE OXIME ESTERS

被引：28

作者：

PULIDO, R ^{[1
]}

GOTOR, V ^{[1
]}

机构：

[1] UNIV OVIEDO,FAC QUIM,DEPT QUIM ORGAN & INORGAN,E-33071 OVIEDO,SPAIN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1993年 / 05期

关键词：

D O I：

10.1039/p19930000589

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Hexoses and pentoses have been alkoxycarbonylated with different preparations of Candida antarctica lipase, using acetone O-(alkoxycarbonyl)oximes. A wide variety of alkoxycarbonyl groups are introduced in an easy manner at the primary hydroxy group of several pentoses and hexoses. Of especial importance are the introduction of allyloxy- and benzyloxy-carbonyl groups.

引用

页码：589 / 592

页数：4

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