MODIFIED ENTRAINMENT METHOD AND ITS APPLICATION TO THE STUDY OF HETEROGENEOUS REACTIONS

被引：8

作者：

FAKTOR, MM

GARRETT, I

LYONS, MH

机构：

来源：

JOURNAL OF CRYSTAL GROWTH | 1979年 / 46卷 / 01期

关键词：

D O I：

10.1016/0022-0248(79)90103-9

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The modified entrainment method is a simple and revealing means of investigating potential chemical vapour transport systems, and in favourable cases may provide thermochemical data for the reactions. In this paper we extend the theory underlying the method showing how we may, by altering the experimental conditions, study the surface kinetics. A simple expression is obtained relating a measured rate of weight loss with a single kinetic parameter - the exchange current. In the light of this discussion some experimental results obtained from the GaAs/HBr system are analysed. © 1979.

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页码：21 / 30

页数：10

相关论文

共 12 条

[1] MODIFIED ENTRAINMENT METHOD FOR MEASURING VAPOR-PRESSURES AND HETEROGENEOUS EQUILIBRIUM-CONSTANTS .4. GALLIUM ARSENIDE HYDROGEN CHLORIDE SYSTEM [J].

BATTAT, D ;

FAKTOR, MM ;

GARRETT, I ;

MOSS, RH .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1974, 70 :2302-2312

[2] MODIFIED ENTRAINMENT METHOD FOR MEASURING VAPOR-PRESSURES AND HETEROGENEOUS EQUILIBRIUM-CONSTANTS .1. THEORY, AND VALIDATION OF METHOD USING WATER AND LEAD [J].

BATTAT, D ;

FAKTOR, MM ;

GARRETT, I ;

MOSS, RH .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1974, 70 :2267-2279

[3] GROWTH OF CRYSTALS FROM GAS PHASE .1. DIFFUSIONAL LIMITATIONS AND INTERFACIAL STABILITY IN CRYSTAL GROWTH BY DISSOCIATIVE SUBLIMATION [J].

FAKTOR, MM ;

HECKINGB.R ;

GARRETT, I .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1970, (16) :2657-&

[4] GROWTH OF CRYSTALS FROM GAS PHASE .2. DIFFUSIONAL LIMITATIONS AND INTERFACIAL STABILITY IN CRYSTAL GROWTH BY DISSOCIATIVE SUBLIMATION, WITH AN INERT THIRD GAS PRESENT [J].

FAKTOR, MM ;

HECKINGB.R ;

GARRETT, I .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1971, (01) :1-&

[5] THERMODYNAMIC STUDY OF CHEMICAL VAPOR TRANSPORT-SYSTEM GAAS-HBR USING A MODIFIED ENTRAINMENT METHOD [J].

FAKTOR, MM ;

GARRETT, I ;

LYONS, MH ;

MOSS, RH .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1977, 73 :1446-1453

[6] RAPID, QUANTITATIVE EXPLORATION OF CHEMICAL-TRANSPORT REACTIONS [J].

FAKTOR, MM ;

GARRETT, I .

JOURNAL OF CRYSTAL GROWTH, 1977, 38 (02) :213-220

[7]

Hayward DO., 1964, CHEMISORPTION

[8] PREPARATION OF HIGH PURITY GALLIUM ARSENIDE BY VAPOUR PHASE EPITAXIAL GROWTH [J].

KNIGHT, JR ;

EFFER, D ;

EVANS, PR .

SOLID-STATE ELECTRONICS, 1965, 8 (02) :178-&

[9] VAPOR-PHASE EQUILIBRIA IN SYSTEMS IN-INCL3 AND GA-GACL3 [J].

KUNIYA, Y ;

HOSAKA, M .

JOURNAL OF CRYSTAL GROWTH, 1975, 28 (03) :385-391

[10] The vapor pressure of metallic tungsten [J].

Langmuir, I .

PHYSICAL REVIEW, 1913, 2 (05) :329-342