MONOMERIC BASE-STABILIZED PHOSPHINOALANES AND ARSINOALANES

被引：31

作者：

ATWOOD, DA ^{[1
]}

CONTRERAS, L ^{[1
]}

COWLEY, AH ^{[1
]}

JONES, RA ^{[1
]}

MARDONES, MA ^{[1
]}

机构：

[1] UNIV TEXAS,DEPT CHEM & BIOCHEM,AUSTIN,TX 78712

来源：

ORGANOMETALLICS | 1993年 / 12卷 / 01期

关键词：

D O I：

10.1021/om00025a008

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first base-stabilized phosphino- and arsinoalane monomers, H2AlEMes2.NMe3 (Mes = Mesityl; 1, E = P; 2, E = As) have been prepared. Thermolysis at 95-degrees-C converts 1 to the trimer [H2AlPMes2]3(3);further heating at 125-degrees-C results in the formation of Mes2PH and aluminum metal.

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页码：17 / 18

页数：2

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