N-HALOGENO COMPOUNDS .14. TRANSFER FLUORINATION OF QUINUCLIDINE USING F-TEDA-BF4 (SELECTOR(TM) REAGENT) - LABORATORY SYNTHESIS OF N-FLUOROQUINUCLIDINIUM SALTS NOT REQUIRING THE USE OF ELEMENTAL FLUORINE

被引：36

作者：

ABDULGHANI, M

BANKS, RE

BESHEESH, MK

SHARIF, I

SYVRET, RG

机构：

[1] UNIV MANCHESTER,INST SCI & TECHNOL,DEPT CHEM,MANCHESTER M60 1QD,LANCS,ENGLAND

[2] AIR PROD & CHEM INC,CTR CORP SCI & TECHNOL,ALLENTOWN,PA 18195

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1995年 / 73卷 / 02期

关键词：

N-HALOGENO COMPOUNDS; QUINUCLIDINE; SYNTHESIS;

D O I：

10.1016/0022-1139(94)03225-O

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

N-Fluoroquinuclidinium tetrafluoroborate (Ib) has been prepared in excellent yield by ''transfer fluorination'' of quinuclidine with 1-chloromethyl-4-fluoro-1,4-diazoniabicyclo [ 2.2.2] octanebis(tetrafluoroborate) (F-TEDA BF4, Selectfluor(TM) reagent), which will also effect N-fluorination of pyridine and 2,4,6-trimethylpyridine.

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页码：255 / 257

页数：3

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