HYDROZIRCONATION OF OLEYL SULFIDES AND OLEYL PHENYLSULPHONE

被引：7

作者：

KARLSSON, S

HALLBERG, A

GRONOWITZ, S

机构：

[1] UNIV LUND,CTR CHEM,DIV ORGAN CHEM 1,POB 124,S-22100 LUND,SWEDEN

[2] UNIV UPPSALA,CTR BIOMED,DEPT ORGAN PHARMACEUT CHEM,S-75123 UPPSALA,SWEDEN

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1992年 / 430卷 / 01期

关键词：

D O I：

10.1016/0022-328X(92)80095-F

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The hydrozirconation of 9-(Z)-octadecenylmethyl-sulphide, 9-(Z)-octadecenyl phenyl sulphide and 9-(Z)-octadecenyl phenyl sulphone have been studied. These compounds underwent substantial elimination of the functional group, yielding after hydrolysis, along with saturated and unsaturated sulphides and sulphones, large amounts of octadecane. The saturated analogues (dodecylmethyl-sulphide, octadecyl phenyl sulphide and octadecyl phenyl sulphone) were unaffected by the hydrozirconation reagent under similar conditions.

引用

页码：53 / 60

页数：8

共 37 条

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