COORDINATION CHEMISTRY OF ANTIMONY AND BISMUTH - LEWIS ACIDITY, SIGMA-ASTERISK-ORBITALS AND COORDINATION GEOMETRY

被引：42

作者：

NORMAN, NC

机构：

[1] The University of Newcastle upon Tyne, Department of Chemistry, Newcastle upon Tyne

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1994年 / 87卷 / 1-4期

关键词：

ANTIMONY; BISMUTH; COORDINATION COMPLEXES; STRUCTURE; BONDING;

D O I：

10.1080/10426509408037451

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Aspects of the coordination chemistry of antimony and bismuth trihalides and phenyl bismuth dihalides with phosphine and ether ligands are discussed together with a description of the bonding in these complexes. The bonding model described provides a rationalisation of the coordination geometries and the observed trends in some of the bond lengths and angles.

引用

页码：167 / 176

页数：10

共 13 条

[11] CHEMICAL BONDING IN HYPERVALENT MOLECULES - THE DOMINANCE OF IONIC BONDING AND NEGATIVE HYPERCONJUGATION OVER D-ORBITAL PARTICIPATION [J].

REED, AE ;

SCHLEYER, PV .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (04) :1434-1445

[12]

SHELDRICK WS, 1991, Z NATURFORSCH B, V46, P639

[13] STEREOCHEMICALLY ACTIVE OR INACTIVE LONE PAIR ELECTRONS IN SOME 6-COORDINATE, GROUP-15 HALIDES [J].

WHEELER, RA ;

KUMAR, PNVP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (12) :4776-4784

← 1 2 →