REACTION OF ALKYNE HAVING HYDROXYPHENYL GROUP WITH MO(CO)(6)

被引：53

作者：

KANETA, N

HIRAI, T

MORI, M

机构：

[1] HOKKAIDO UNIV,FAC PHARMACEUT SCI,SAPPORO,HOKKAIDO 060,JAPAN

[2] OSAKA CITY UNIV,FAC SCI,OSAKA 558,JAPAN

来源：

CHEMISTRY LETTERS | 1995年 / 08期

关键词：

D O I：

10.1246/cl.1995.627

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of m-and p-hydroxyphenylpropyne, 1a and 1b, with Mo(CO)(6) (5 mol%) affords metathesis products, 2a and 2b, in 78% and 14% (conversion yield, 78%) yields, respectively. However, o-hydroxyphenylpropyne 1f gave trimerization product 4 in 65% yield.

引用

页码：627 / 628

页数：2

共 26 条

[1] REACTIVITY OF THE TUNGSTEN CARBYNE W(CCH3)CL(PME3)4 - DOUBLE CARBONYLATION, CARBYNE ALKYNE COMPLEXES, AND STOICHIOMETRIC ACETYLENE METATHESIS
ATAGI, LM
CRITCHLOW, SC
MAYER, JM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (23) : 9223 - 9224
[2] METATHESIS VS POLYMERIZATION OF TERMINAL ACETYLENES OVER [W(CBUT)(OBUT)3]
BRAY, A
MORTREUX, A
PETIT, F
PETIT, M
SZYMANSKA-BUZAR, T
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (02) : 197 - 199
[3] RUTHENIUM-CATALYZED REACTION OF 1,6-DIYNES WITH HYDROSILANES AND CARBON-MONOXIDE - A 3RD WAY OF INCORPORATING CO
CHATANI, N
FUKUMOTO, Y
MURAI, S
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (24) : 11614 - 11615
[4] HOMOGENEOUS ACETYLENE METATHESIS - NATURE OF THE CATALYTICALLY ACTIVE SPECIES IN THE [MO(CO)6]-PHENOL SYSTEM
DEVARAJAN, S
WALTON, DRM
LEIGH, GJ
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1979, 181 (01) : 99 - 104
[5] A FOLDED METALLACYCLOPENTATRIENE AND A BICAPPED-TETRAHEDRAL M2C4 CLUSTER OBTAINED FROM COUPLING OF ALKYNE LIGANDS - STRUCTURES OF CPMOCL(C4PH4) AND (CPMOCL)2(MU-ETA-4-C4 PARA-TOLYL4)
HIRPO, W
CURTIS, MD
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (15) : 5218 - 5219
[6] KESCHNER JL, 1988, J AM CHEM SOC, V110, P8235
[7] KESCHNER JL, 1987, J AM CHEM SOC, V109, P5840
[8] COORDINATION AND OLIGOMERIZATION OF ALKYNES AT MONONUCLEAR TUNGSTEN ARYLOXIDE METAL CENTERS
KRILEY, CE
KERSCHNER, JL
FANWICK, PE
ROTHWELL, IP
[J]. ORGANOMETALLICS, 1993, 12 (06) : 2051 - 2058
[9] PREPARATION OF POLYCYCLOOCTYNE BY RING-OPENING POLYMERIZATION EMPLOYING D0 TUNGSTEN AND MOLYBDENUM ALKYLIDYNE COMPLEXES
KROUSE, SA
SCHROCK, RR
[J]. MACROMOLECULES, 1989, 22 (06) : 2569 - 2576
[10] CARBON-CARBON TRIPLE-BOND FISSION IN THE HOMOGENEOUS CATALYSIS OF ACETYLENE METATHESIS
LEIGH, GJ
RAHMAN, MT
WALTON, DRM
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1982, (10) : 541 - 542

← 1 2 3 →