C-70 IS MORE STABLE THAN C-60 - EXPERIMENTAL-DETERMINATION OF THE HEAT OF FORMATION OF C-70

被引:105
作者
BECKHAUS, HD
VEREVKIN, S
RUCHARDT, C
DIEDERICH, F
THILGEN, C
TERMEER, HU
MOHN, H
MULLER, W
机构
[1] ETH ZURICH,ORGAN CHEM LAB,CH-8092 ZURICH,SWITZERLAND
[2] HOECHST AG,D-65926 FRANKFURT,GERMANY
来源
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 09期
关键词
D O I
10.1002/anie.199409961
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
C70, C60,…, diamond, graphite. The accurate calorimetric determination of the standard heats of formation of highly pure C60 and C70 confirms the fundamental statements concerning the stability in the series of the allotropic forms of carbon predicted from calculations. MM3 force‐field calculations provide the best prediction of the experimental values. Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany
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页码:996 / 998
页数:3
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