AN ALKYNE GROUP WITH A PAIR OF HYDROGEN-BONDS - THE CRYSTAL-STRUCTURE OF 2,2'-ETHYNYLENEDIBENZENEBORONIC ACID AT 122 K

被引：26

作者：

PILKINGTON, M

WALLIS, JD

LARSEN, S

机构：

[1] UNIV COPENHAGEN,CTR CRYSTALLOG STUDIES,DEPT CHEM,DK-2100 COPENHAGEN,DENMARK

[2] UNIV KENT,CTR MAT RES,CHEM LAB,CANTERBURY CT2 7NH,KENT,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 15期

关键词：

D O I：

10.1039/c39950001499

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

For each boronic acid group in 1 one hydrogen atom makes a hydrogen bond to an alkyne carbon atom as well as an intermolecular O-H...O bond; structural effects indicate the boronic acid group to be sigma-electron releasing and pi-electron withdrawing.

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收藏

页码：1499 / 1500

页数：2

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