O-H ... PI(ARENE) INTERMOLECULAR HYDROGEN-BONDING IN THE STRUCTURE OF 1,1,2-TRIPHENYLETHANOL

被引：31

作者：

FERGUSON, G ^{[1
]}

GALLAGHER, JF ^{[1
]}

GLIDEWELL, C ^{[1
]}

ZAKARIA, CM ^{[1
]}

机构：

[1] UNIV ST ANDREWS,SCH CHEM,ST ANDREWS KY16 9ST,FIFE,SCOTLAND

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1994年 / 50卷

关键词：

D O I：

10.1107/S0108270193007164

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The 1,1,2-triphenylethanol molecule, Ph2(PhCH2)COH (1), forms centrosymmetric dimers in the solid state. The shortest O ... O separation, 5.837 (3) angstrom, is too long for any O-H ... O hydrogen-bond formation. Instead, there are O-H ... pi(arene) interactions between the hydroxyl group of one molecule and a phenyl group of a centrosymmetrically related molecule. The O ... C and H ... C distances between the hydroxyl group and the closest phenyl-ring C atom are 3.525 (4) and 2.73 (4) angstrom, respectively. These intermolecular contacts are the only driving force towards dimer formation in the solid state.

引用

页码：70 / 73

页数：4

共 20 条

[1] [Anonymous], 1970, CRYSTALLOGRAPHIC COM
[2] ALUMINUM-FUSED BIS-PARA-TERT-BUTYLCALIX[4]ARENE - A DOUBLE CONE WITH 2 PI-ARENE...H INTERACTIONS FOR INCLUDED METHYLENE-CHLORIDE
ATWOOD, JL
BOTT, SG
JONES, C
RASTON, CL
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (18) : 1349 - 1351
[3] X-RAY-DIFFRACTION EVIDENCE FOR AROMATIC PI HYDROGEN-BONDING TO WATER
ATWOOD, JL
HAMADA, F
ROBINSON, KD
ORR, GW
VINCENT, RL
[J]. NATURE, 1991, 349 (6311) : 683 - 684
[4] CRYSTAL-STRUCTURE OF TRIBUTYLAMMONIUM TETRAPHENYLBORATE MONOHYDRATE - EXAMPLE FOR H-PI INTERACTION
AUBRY, A
PROTAS, J
MORENOGONZALEZ, E
MARRAUD, M
[J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1977, 33 (AUG15): : 2572 - 2578
[5] SYNTHESIS AND X-RAY MOLECULAR-STRUCTURES OF P-TERT-BUTYLCALIX[4]ARENES WITH DIAMIDE BRIDGES SPANNING THE 1,3-(DISTAL) POSITIONS ON THE LOWER RIM
BOHMER, V
FERGUSON, G
GALLAGHER, JF
LOUGH, AJ
MCKERVEY, MA
MADIGAN, E
MORAN, MB
PHILLIPS, J
WILLIAMS, G
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1993, (13): : 1521 - 1527
[6] ENRAFNONIUS, 1989, CAD4 SOFTWARE VERSIO
[7] ENCODING AND DECODING HYDROGEN-BOND PATTERNS OF ORGANIC-COMPOUNDS
ETTER, MC
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1990, 23 (04) : 120 - 126
[8] HYDROGEN-BOND DIRECTED COCRYSTALLIZATION AND MOLECULAR RECOGNITION PROPERTIES OF ACYCLIC IMIDES
ETTER, MC
REUTZEL, SM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (07) : 2586 - 2598
[9] GRAPH-SET ANALYSIS OF HYDROGEN-BOND PATTERNS IN ORGANIC-CRYSTALS
ETTER, MC
MACDONALD, JC
BERNSTEIN, J
[J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS, 1990, 46 : 256 - 262
[10] STRUCTURES OF 1-FERROCENYL-1-PHENYLETHANOL, FERROCENYL(DIPHENYL)METHANOL AND FERROCENE-1,1'-DIYLBIS(DIPHENYLMETHANOL)
FERGUSON, G
GALLAGHER, JF
GLIDEWELL, C
ZAKARIA, CM
[J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1993, 49 : 967 - 971

← 1 2 →