TRANSITION STRUCTURES FOR RADICAL HYDROGEN ABSTRACTIONS AND LITHIUM HYDRIDE ADDITIONS - SIMILITUDES AND DIVARICATIONS

被引：18

作者：

EKSTEROWICZ, JE ^{[1
]}

HOUK, KN ^{[1
]}

机构：

[1] UNIV CALIF LOS ANGELES,DEPT CHEM & BIOCHEM,LOS ANGELES,CA 90024

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 03期

关键词：

D O I：

10.1016/0040-4039(93)85093-C

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Ab initio transition structures were obtained for the reactions of methane and hydrogen sulfide with the 1-hydroxyethyl radical, lithium hydride with acetaldehyde, hydrogen sulfide with 2-hydroxy-3-methylbutan-2-yl, and lithium hydride with methyl isopropyl ketone.

引用

页码：427 / 430

页数：4

共 8 条

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[5] HOUK KN, 1987, STEREOCHEMISTRY ORGA, P247
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[7] STEREOSELECTIVITIES OF NUCLEOPHILIC ADDITIONS TO CYCLOHEXANONES SUBSTITUTED BY POLAR GROUPS - EXPERIMENTAL INVESTIGATION OF REDUCTIONS OF TRANS-DECALONES AND THEORETICAL-STUDIES OF CYCLOHEXANONE REDUCTIONS - THE INFLUENCE OF REMOTE ELECTROSTATIC EFFECTS
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HOUK, KN
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (13) : 5018 - 5027
[8] ELECTRONIC AND CONFORMATIONAL EFFECTS ON PI-FACIAL STEREOSELECTIVITY IN NUCLEOPHILIC ADDITIONS TO CARBONYL-COMPOUNDS
WU, YD
HOUK, KN
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (03) : 908 - 910

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