A NOVEL-APPROACH TO STRUCTURE FLAMMABILITY CORRELATION IN POLYPHOSPHATE ESTERS

被引:77
作者
ANNAKUTTY, KS
KISHORE, K
机构
关键词
Mathematical Models - Phosphates - Polymers--Molecular Structure;
D O I
10.1016/0032-3861(88)90055-9
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The relationship between the structure and flammability of a number of polyphosphate esters has been examined. The conventional correlation of char residue with limiting oxygen index was found to be unproductive in these polymers, giving insight into the importance of gas phase reactions in addition to condensed phase reactions in determining their flammability. A novel approach was sough in understanding the structure-flammability relationships of these polymers relating thermal stability, phosphorus content and limiting oxygen index. An empirical relationship has been derived amongst these three paramters.
引用
收藏
页码:1273 / 1276
页数:4
相关论文
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