SOLUTION STRUCTURE AND DYNAMICS OF DTPA-LN(III) COMPLEXES (DTPA = DIETHYLENE TRIAMINE PENTA ACETATE, LN = LA, PR, EU)

被引：47

作者：

AIME, S

BOTTA, M

机构：

[1] Dipartimento di Chimica Inorganica, Chimica Fizica e Chimica dei Materiali Università di Torino, 10125 Turin

来源：

INORGANICA CHIMICA ACTA | 1990年 / 177卷 / 01期

关键词：

D O I：

10.1016/S0020-1693(00)91917-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Variable temperature H-1 and C-13 NMR spectra and proton and carbon longitudinal relaxation times allow the complete characterization of the solution structure and dynamics of three Ln(III) complexes of DTPA (Ln = La, Pr and Eu). Our results show that a rapid interconversion between octadentate structures occurs on the NMR time scale which can be 'frozen out' at low temperature for Pr and Eu complexes.

引用

页码：101 / 105

页数：5