Configuration interaction and the spectra of LaCl3 : Pr3+

被引：36

作者：

Morrison, J. C. ^{[1
]}

Fields, P. R. ^{[1
]}

Carnall, W. T. ^{[1
]}

机构：

[1] Argonne Natl Lab, Div Chem, Argonne, IL 60439 USA

来源：

PHYSICAL REVIEW B-SOLID STATE | 1970年 / 2卷 / 09期

关键词：

D O I：

10.1103/PhysRevB.2.3526

中图分类号：

O469 [凝聚态物理学];

学科分类号：

070205 ;

摘要：

Effective operators, which take into account the excitation of a 4f electron to a higher-lying p or f orbital by means of the crystal field, are cast into a form which is convenient for a parametric study. The complete crystal-field matrices of these operators and of the operators that arise in the first-order analysis are diagonalized, and the Stark levels of LaCl3: Pr3+ are fitted parametrically. It is found that when the effect of configuration interaction is absorbed by these new parameters, the ordinary crystal-field parameters change by a small but significant amount.

引用

页码：3526 / 3532

页数：7

共 21 条

[1] CRYSTAL-FIELD-INDUCED CONFIGURATION INTERACTION IN CONFIGURATION (L1 + L2) [J].