FORMATION AND MID-FT-IR INVESTIGATION OF SHORT (C2-C5) STRAIGHT CHAIN TETRAZINC MU-4-OXO-HEXA-MU-CARBOXYLATES

被引：19

作者：

BERKESI, O ^{[1
]}

DREVENI, I ^{[1
]}

ANDOR, JA ^{[1
]}

GOGGIN, PL ^{[1
]}

机构：

[1] UNIV BRISTOL,DEPT INORGAN CHEM,BRISTOL BS8 1TS,AVON,ENGLAND

来源：

INORGANICA CHIMICA ACTA | 1991年 / 181卷 / 02期

关键词：

D O I：

10.1016/S0020-1693(00)86823-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new method for producing tetrazinc mu-4-oxo-hexa-mu-carboxylates of short straight-chain carboxylic acids in solution is reported. The complexes with C2-C5 chain have been prepared. Their characteristic IR bands in the mid-IR region are discussed and give a satisfactory identification method for these complexes. The formation process and the influence of the water present in the system have been monitored by FT-IR spectroscopy. A modified mechanism of formation and decomposition, based on an equilibrium and a 'feedback' step, is proposed.

引用

页码：285 / 289

页数：5

共 17 条

[1]

Auger V, 1924, CR HEBD ACAD SCI, V178, P1546

[2]

BERKESI O, 1989, SURFACTANCTS SOLUTIO, V9, P63

[3]

BERKESI O, 1985, 10TH P C COORD CHEM, P47

[4] MASS-SPECTRA OF TETRACOBALT(II) AND TETRAZINC(II) MU4-OXO-HEXA-MU-CARBOXYLATES (BASIC COBALT AND ZINC CARBOXYLATES) [J].

CHARALAMBOUS, J ;

COPPERTHWAITE, RG ;

JEFFS, SW ;

SHAW, DE .

INORGANICA CHIMICA ACTA, 1975, 14 (01) :53-58

[5] PREPARATION AND CRYSTAL-STRUCTURE OF A CARBOXYLATE-BRIDGED LINEAR TRINUCLEAR ZINC(II) COMPLEX [J].

CLEGG, W ;

LITTLE, IR ;

STRAUGHAN, BP .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1985, (02) :73-74

[6]

DREVENI I, UNPUB VIB SPECTROSC

[7] PREPARATION AND PROPERTIES OF TETRAZINC MU-4-OXOHEXA-MU-CARBOXYLATES (BASIC ZINC CARBOXYLATES) [J].

GORDON, RM ;

SILVER, HB .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1983, 61 (06) :1218-1221

[8] TRI- AND TETRA-NUCLEAR OXY-COMPLEXES [J].

GRIFFITH, WP .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1969, (15) :2270-&

[9] UBER ZINK-OXY-ACETAT [J].

HARDT, HD ;

STAVENOW, F .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1959, 301 (5-6) :267-270

[10] CRYSTAL-STRUCTURE OF MU-4-OXO-HEXAKIS(MU-ACETATO)TETRAZINC AND THERMAL STUDIES OF ITS PRECURSOR, ZINC ACETATE DIHYDRATE [J].

HILTUNEN, L ;

LESKELA, M ;

MAKELA, M ;

NIINISTO, L .

ACTA CHEMICA SCANDINAVICA SERIES A-PHYSICAL AND INORGANIC CHEMISTRY, 1987, 41 (10) :548-555

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