FORMATION AND MID-FT-IR INVESTIGATION OF SHORT (C2-C5) STRAIGHT CHAIN TETRAZINC MU-4-OXO-HEXA-MU-CARBOXYLATES

被引：19

作者：

BERKESI, O ^{[1
]}

DREVENI, I ^{[1
]}

ANDOR, JA ^{[1
]}

GOGGIN, PL ^{[1
]}

机构：

[1] UNIV BRISTOL,DEPT INORGAN CHEM,BRISTOL BS8 1TS,AVON,ENGLAND

来源：

INORGANICA CHIMICA ACTA | 1991年 / 181卷 / 02期

关键词：

D O I：

10.1016/S0020-1693(00)86823-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new method for producing tetrazinc mu-4-oxo-hexa-mu-carboxylates of short straight-chain carboxylic acids in solution is reported. The complexes with C2-C5 chain have been prepared. Their characteristic IR bands in the mid-IR region are discussed and give a satisfactory identification method for these complexes. The formation process and the influence of the water present in the system have been monitored by FT-IR spectroscopy. A modified mechanism of formation and decomposition, based on an equilibrium and a 'feedback' step, is proposed.

引用

页码：285 / 289

页数：5

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