(ALKYLAMIDO)GALLATE COMPLEXES OF THE GROUP-1 AND GROUP-2 ELEMENTS

被引：12

作者：

ATWOOD, DA ^{[1
]}

COWLEY, AH ^{[1
]}

JONES, RA ^{[1
]}

机构：

[1] UNIV TEXAS,DEPT CHEM & BIOCHEM,AUSTIN,TX 78712

来源：

ORGANOMETALLICS | 1993年 / 12卷 / 01期

关键词：

D O I：

10.1021/om00025a040

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of 2 equiv of LiNH(t-Bu) with [Cy2GaCl]2 (Cy = cyclohexyl) produces the gallate complex Li(THF)2(mu-NH(t-Bu))2GaCy2(l). The reaction of 2 equiv of Li(3,5-Me2Pz) (Pz = pyrazolyl) with [Cy2GaCl]2 Produces the gallate species MgCl(THF)2(mu-3,5-Me2Pz)2GaCy2(2). An X-ray structural study shows that the amide ligands for 1 and 2 bridge from the Ga atom to Li+ and MgCl+, respectively.

引用

页码：236 / 238

页数：3

共 17 条

[1] MANGANESE, MOLYBDENUM, AND TUNGSTEN CARBONYL DERIVATIVES INCORPORATING THE DIMETHYLBIS(1-PYRAZOLYL)GALLATE LIGAND, [ME2GA(N2C3H3)2]-
ANSLOW, SE
CHONG, KS
RETTIG, SJ
STORR, A
TROTTER, J
[J]. CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1981, 59 (22): : 3123 - 3135
[2] ATWOOD D, UNPUB
[3] STRUCTURAL CHARACTERIZATION OF A DIALKYLGALLIUM CATION - X-RAY CRYSTAL-STRUCTURE OF [ME2GA(TERT-BUNH2)2]BR
ATWOOD, DA
JONES, RA
COWLEY, AH
BOTT, SG
ATWOOD, JL
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1992, 425 (1-2) : C1 - C3
[4] PRIMARY AMIDE AND AMINE COMPLEXES OF GALLIUM AND INDIUM - X-RAY CRYSTAL-STRUCTURES OF [ME2GA(MU-NH(TBU))]2, ME3GA.NH2(TBU) AND ME3IN.NH2(TBU)
ATWOOD, DA
JONES, RA
COWLEY, AH
BOTT, SG
ATWOOD, JL
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1992, 434 (02) : 143 - 150
[5] SYNTHESIS AND STRUCTURES OF 2 BULKY GALLIUM CHLORIDES
ATWOOD, DA
COWLEY, AH
JONES, RA
MARDONES, MA
[J]. JOURNAL OF COORDINATION CHEMISTRY, 1992, 25 (03) : 233 - 239
[6] PRIMARY AMIDO AND AMINE ADDUCT COMPLEXES OF GALLIUM - SYNTHESIS AND STRUCTURES OF [TERT-BU2GA(MU-NHPH)]2 AND TERT-BU3GA.NH2PH
ATWOOD, DA
JONES, RA
COWLEY, AH
BOTT, SG
ATWOOD, JL
[J]. POLYHEDRON, 1991, 10 (16) : 1897 - 1902
[7] THE CHEMISTRY OF TRICHLORO[TRIS(TRIMETHYLSILYL)METHYL] AND TRICHLORO[TRIS(DIMETHYLPHENYLSILYL)METHYL] COMPLEXES OF GALLIUM, INDIUM, AND THALLIUM - CRYSTAL AND MOLECULAR-STRUCTURES OF [LI(THF)2(MU-CL)2GACL-(C(SIME2PH)3)].THF, [LI(THF)3(MU-CL)INCL2(C(SIME3)3)], AND [((ME3SI)3C)IN(MU-CL)2(MU-FE(CO)4)IN(C(SIME3)3)] (THF = TETRAHYDROFURAN)L
ATWOOD, JL
BOTT, SG
HITCHCOCK, PB
EABORN, C
SHARIFFUDIN, RS
SMITH, JD
SULLIVAN, AC
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1987, (04): : 747 - 755
[8] ALKYL-BRIDGED COMPLEXES OF THE D-BLOCK AND F-BLOCK ELEMENTS .1. DI-MU-ALKYL-BIS(ETA-CYCLOPENTADIENYL)METAL(III)DIALKYLALUMINIUM(III) COMPLEXES AND THE CRYSTAL AND MOLECULAR-STRUCTURE OF THE YTTERBIUM METHYL SPECIES
HOLTON, J
LAPPERT, MF
BALLARD, DGH
PEARCE, R
ATWOOD, JL
HUNTER, WE
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1979, (01): : 45 - 53
[9] SYNTHESIS AND CHARACTERIZATION OF [ME2GA(3,5-ME2PZ)2]RH(CO)PPH3 AND THE X-RAY STRUCTURE OF ITS TOLUENE SOLVATE
LOUIE, BM
RETTIG, SJ
STORR, A
TROTTER, J
[J]. CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1985, 63 (02): : 503 - 508
[10] RHENIUM CARBONYL DERIVATIVES INCORPORATING THE BIDENTATE CHELATING PYRAZOLYL GALLATE LIGANDS, [ME2GA(N2C3HR2)2]- AND [ME2GA(N2C3HR2)(OH)]- (WHERE R = H OR ME)
LOUIE, BM
STORR, A
[J]. CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1984, 62 (07): : 1344 - 1348

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