SOLVOMERCURATION-DEMERCURATION OF LIMONENE WITH HG(BF4)2 - A CHEMOSPECIFIC AND REGIOSPECIFIC ROUTE TO 8-SUBSTITUTED PARA-MENTHENES

被引：9

作者：

DEMATTOS, MCS

KOVER, WB

AZNAR, F

BARLUENGA, J

机构：

[1] UNIV FED RIO DE JANEIRO,INST QUIM,DEPT QUIM ORGAN,BR-21945 RIO DE JANEIRO,BRAZIL

[2] UNIV ESTADO RIO DE JANEIRO,INST QUIM,DEPT QUIM ORGAN,BR-20551 RIO DE JANEIRO,BRAZIL

[3] UNIV OVIEDO,FAC QUIM,DEPT QUIM ORGANOMET,E-33071 OVIEDO,SPAIN

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 34期

关键词：

LIMONENE; MERCURATION-DEMERCURATION; ALPHA-TERPINEOL; MERCURIC TETRAFLUOROBORATE; PARA-MENTHENES;

D O I：

10.1016/S0040-4039(00)61218-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Solvomercuration-demercuration of limonene with equimolar Hg(BF4)2 and excess nucleophile (-20-degrees-C) functionalizes the acyclic double bond and provides specifically 8-substituted p-menthenes.

引用

页码：4863 / 4866

页数：4

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