共 11 条
[11]
PAWSON BA, 1968, J CHEM SOC CHEM COMM, P1057
SOLVOMERCURATION-DEMERCURATION OF LIMONENE WITH HG(BF4)2 - A CHEMOSPECIFIC AND REGIOSPECIFIC ROUTE TO 8-SUBSTITUTED PARA-MENTHENES
被引：9
作者：
DEMATTOS, MCS
KOVER, WB
AZNAR, F
BARLUENGA, J
机构：
[1] UNIV FED RIO DE JANEIRO,INST QUIM,DEPT QUIM ORGAN,BR-21945 RIO DE JANEIRO,BRAZIL
[2] UNIV ESTADO RIO DE JANEIRO,INST QUIM,DEPT QUIM ORGAN,BR-20551 RIO DE JANEIRO,BRAZIL
[3] UNIV OVIEDO,FAC QUIM,DEPT QUIM ORGANOMET,E-33071 OVIEDO,SPAIN
关键词：
LIMONENE;
MERCURATION-DEMERCURATION;
ALPHA-TERPINEOL;
MERCURIC TETRAFLUOROBORATE;
PARA-MENTHENES;
D O I：
10.1016/S0040-4039(00)61218-2
中图分类号：
O62 [有机化学];
学科分类号：
070303 ;
081704 ;
摘要：
Solvomercuration-demercuration of limonene with equimolar Hg(BF4)2 and excess nucleophile (-20-degrees-C) functionalizes the acyclic double bond and provides specifically 8-substituted p-menthenes.
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页码：4863 / 4866
页数：4
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