CHIRAL CYCLOPALLADATED COMPOUNDS FOR ENANTIOMERIC PURITIES OF FUNCTIONALIZED PHOSPHINES BY MEANS OF MULTINUCLEAR NMR

被引：56

作者：

ALBERT, J

GRANELL, J

MULLER, G

SAINZ, D

FONTBARDIA, M

SOLANS, X

机构：

[1] UNIV BARCELONA,DEPT QUIM INORGAN,E-08028 BARCELONA,SPAIN

[2] UNIV BARCELONA,DEPT CRISTALLOG & DIPOSITS MINERALS,E-08028 BARCELONA,SPAIN

来源：

TETRAHEDRON-ASYMMETRY | 1995年 / 6卷 / 02期

关键词：

D O I：

10.1016/0957-4166(95)00004-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The application of the cyclopalladated compound [Pd(2-{Z-(R)-CHMeN=CH-2',6'-Cl2C6H3}C6H4)Cl](2) for the enantiomeric excess determination of functionalized phosphines is presented. The X-ray structure determination of diastereomeric complex [Pd(2-{Z-(R)-CHMeN=CH-2',6'-Cl2C6H3]C6H4)Cl{(R,R)-PPh(2)(2-OHC6H1 0)}] is also reported.

引用

页码：325 / 328

页数：4

共 13 条

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