NOVEL ATROPISOMERIC PHOSPHORUS LIGANDS - 4,5-DIHYDRO-3H-DINAPHTHO[2,1-C,1',2'-E]PHOSPHEPINE DERIVATIVES

被引：139

作者：

GLADIALI, S

DORE, A

FABBRI, D

DELUCCHI, O

MANASSERO, M

机构：

[1] UNIV VENICE,DIPARTIMENTO CHIM,I-30123 VENICE,ITALY

[2] UNIV MILAN,IST CHIM STRUTTURIST INORGAN,I-20133 MILAN,ITALY

来源：

TETRAHEDRON-ASYMMETRY | 1994年 / 5卷 / 04期

关键词：

D O I：

10.1016/0957-4166(94)80005-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Atropisomerically pure (S)-4-phenyl-4,5-dihydro-3H-dinaphtho[2,1-c;1',2'-e]phosphepine 2b has been obtained by resolution of the racemic compound with an enantiopure palladium complex and its absolute configuration has been determined by X-ray analysis; it is an effective chiral ligand for the asymmetric hydroformylation of styrene with rhodium catalysts.

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页码：511 / 514

页数：4

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