REACTIONS OF [(C(5)ME(5))ZRF3] WITH ALME(3) - SYNTHESIS AND STRUCTURE OF A ZIRCONIUM-ALUMINUM-CARBON CLUSTER

被引：54

作者：

HERZOG, A ^{[1
]}

ROESKY, HW ^{[1
]}

ZAK, Z ^{[1
]}

NOLTEMEYER, M ^{[1
]}

机构：

[1] UNIV GOTTINGEN,INST ANORGAN CHEM,D-37077 GOTTINGEN,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 09期

关键词：

D O I：

10.1002/anie.199409671

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Transfer of methyl groups from 2 to 1 leads to the first Zr3Al6C7 cluster 3 [Eq. (a)], in which six metal atoms form an open cube shielded by Al and C atoms. The ZrAl distances in the cube are remarkably short. Zr/Al/C compounds are of interest with regard to Ziegler–Natta catalysts. (Formula Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：967 / 968

页数：2

共 16 条

[1] THE TETRAMERIC ALUMINUM(I) COMPOUND [(AL(ETA-5-C5ME5))4]
DOHMEIER, C
ROBL, C
TACKE, M
SCHNOCKEL, H
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1991, 30 (05): : 564 - 565
[2] DOHMEIER C, 1991, ANGEW CHEM, V103, P593
[3] NOVEL SYNTHETIC ROUTE TO HYDROCARBYL-BRIDGED DINUCLEAR ZIRCONIUM ALUMINUM COMPLEXES EXHIBITING A PLANAR TETRACOORDINATE CARBON CENTER
ERKER, G
ALBRECHT, M
KRUGER, C
WERNER, S
[J]. ORGANOMETALLICS, 1991, 10 (11) : 3791 - 3793
[4] THE 1ST STABLE ZIRCONIUM ALKYLIDENE COMPLEX FORMED VIA ALPHA-HYDROGEN ABSTRACTION - SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF [ETA-5-C5H3-1,3-(SIME2CH2PPR(I)2)2]ZR=CHPH(CL)
FRYZUK, MD
MAO, SSH
ZAWOROTKO, MJ
MACGILLIVRAY, LR
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (12) : 5336 - 5337
[5] MOLECULAR-STRUCTURE OF DIMETHYLALUMINUM FLUORIDE TETRAMER, [(CH3)2A1F]4
GUNDERSEN, G
HAUGEN, T
HAALAND, A
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1973, 54 (JUN16) : 77 - 86
[6] HERZOG A, 1994, IN PRESS ORGANOMETAL
[7] HERZOG A, UNPUB
[8] THE SEARCH FOR DIMETHYLZIRCONOCENE - CRYSTAL-STRUCTURES OF DIMETHYLZIRCONOCENE, DIMETHYLHAFNOCENE, CHLOROMETHYLZIRCONOCENE, AND (MU-OXO)BIS(METHYLZIRCONOCENE)
HUNTER, WE
HRNCIR, DC
BYNUM, RV
PENTTILA, RA
ATWOOD, JL
[J]. ORGANOMETALLICS, 1983, 2 (06) : 750 - 755
[9] POLYMERIZATION OF PROPENE AND BUTENE WITH A CHIRAL ZIRCONOCENE AND METHYLALUMOXANE AS COCATALYST
KAMINSKY, W
KULPER, K
BRINTZINGER, HH
WILD, FRWP
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1985, 24 (06) : 507 - 508
[10] KAMINSKY W, 1993, ORGANIC SYNTHESIS VI, P151

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