NOVEL TETRANUCLEAR NICKEL(II) COMPLEX WITH A MIXED-SPIN STATE GENERATED BY PAIRING OF DIMERS

被引：16

作者：

MIKURIYA, M

NAKADERA, K

KOTERA, T

机构：

来源：

CHEMISTRY LETTERS | 1993年 / 04期

关键词：

D O I：

10.1246/cl.1993.637

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A tetranuclear nickel(II) complex with 2,6-bis(salicylideneaminomethyl)-4-methylphenol (H3L), [Ni4(L)2(Pz)2(CH3OH)] (pz=pyrazolate ion) has been synthesized and characterized by electronic spectra and magnetic susceptibilites (80-300 K). The X-ray crystal structure analysis has demonstrated that it consists of tetranuclear (low-spin-high-spin-high-spin-low-spin) molecules with a zigzag structure.

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页码：637 / 640

页数：4

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