TERMINAL E(1) LIGANDS FROM ELEMENTS OF GROUP-15

被引：33

作者：

SCHEER, M

机构：

[1] Institut für Anorganische Chemie, Universität Karlsruhe, D-76128, Engesserstrasse

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 18期

关键词：

COMPLEXES WITH ELEMENTS OF GROUP 15; MOLYBDENUM COMPOUNDS; MULTIPLE BONDS; PHOSPHORUS COMPOUNDS; TUNGSTEN COMPOUNDS;

D O I：

10.1002/anie.199519971

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

From objects of speculation to manipulable compounds: Two research groups have achieved the synthesis of the long sought metal complexes with terminal phosphido (P3−) ligands by independent routes, and both papers can be found in this issue of Angewandle Chemie. Cummins et al. report on the synthesis of 1 on p. 2042ff, Schrock et al. on the synthesis of 2 on p. 2044ff. Together with phosphaalkynes RCP these are the first compounds with a singly coordinated phosphorus and will be of interest to theoreticians and preparative chemists alike. R = C(CD3)2CH3; Ar = 3,5‐C6H3Me2; N3N = (Me3SiNCH2CH2)3N; M = Mo, W. (Formula Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1997 / 1999

页数：3

共 49 条

[21] CRYSTAL-STRUCTURE OF NITRIDO TETRACHLORO MOLYBDATE(VI), [(C6H5)4AS][MONCL4], AND HYDROLYSIS TO ISOTYPIC OXO TETRACHLORO MOLYBDATE(V), [(C6H5)4AS][MOOCL4] [J].