A COVALENT BOND TO BROMINE IN HBR-TREATED POLYANILINE FROM X-RAY-DIFFRACTION

被引:30
作者
ANNIS, BK [1 ]
NARTEN, AH [1 ]
MACDIARMID, AG [1 ]
RICHTER, AF [1 ]
机构
[1] UNIV PENN,DEPT CHEM,PHILADELPHIA,PA 19104
关键词
ELECTRIC CONDUCTIVITY - HYDROGEN INORGANIC COMPOUNDS - X-RAYS - Diffraction;
D O I
10.1016/0379-6779(88)90216-0
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
When the emeraldine base form of polyaniline is doped by aqueous HBr, the conductivity is increased to 2 (ohm cm)** minus **1 for a compressed pellet. X-ray diffraction results on the conducting polymer together with elemental analysis indicate that a significant portion of the bromine is covalently bound.
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页码:191 / 199
页数:9
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