A COVALENT BOND TO BROMINE IN HBR-TREATED POLYANILINE FROM X-RAY-DIFFRACTION

被引：30

作者：

ANNIS, BK ^{[1
]}

NARTEN, AH ^{[1
]}

MACDIARMID, AG ^{[1
]}

RICHTER, AF ^{[1
]}

机构：

[1] UNIV PENN,DEPT CHEM,PHILADELPHIA,PA 19104

来源：

SYNTHETIC METALS | 1988年 / 22卷 / 03期

关键词：

ELECTRIC CONDUCTIVITY - HYDROGEN INORGANIC COMPOUNDS - X-RAYS - Diffraction;

D O I：

10.1016/0379-6779(88)90216-0

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

When the emeraldine base form of polyaniline is doped by aqueous HBr, the conductivity is increased to 2 (ohm cm)** minus **1 for a compressed pellet. X-ray diffraction results on the conducting polymer together with elemental analysis indicate that a significant portion of the bromine is covalently bound.

引用

页码：191 / 199

页数：9

共 26 条

[11] DIRECT DETERMINATION OF MOLECULAR STRUCTURE - CRYSTAL STRUCTURE OF HIMBACINE HYDROBROMIDE AT - 150 DEGREES C
FRIDRICHSONS, J
MATHIESON, AM
[J]. ACTA CRYSTALLOGRAPHICA, 1962, 15 (FEB): : 119 - &
[12] HAGIWARA T, IN PRESS SYNTH MET
[13] STUDIES ON NITROGEN-BROMINE COMPOUNDS .4. X-RAY STRUCTURAL-ANALYSIS OF ORGANIC N-BR COMPOUNDS FOR MAKING VISIBLE GENERAL STRUCTURE ELEMENTS OF BROM-AMINES
JABAY, O
PRITZKOW, H
JANDER, J
[J]. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1977, 32 (12): : 1416 - 1420
[14] X-RAY DIFFRACTOMETRY WITH SLIGHTLY ABSORBING SAMPLES
LEVY, HA
AGRON, PA
DANFORD, MD
[J]. JOURNAL OF APPLIED PHYSICS, 1959, 30 (12) : 2012 - 2013
[15] POLYANILINE - A NEW CONCEPT IN CONDUCTING POLYMERS
MACDIARMID, AG
CHIANG, JC
RICHTER, AF
EPSTEIN, AJ
[J]. SYNTHETIC METALS, 1987, 18 (1-3) : 285 - 290
[16] POLYANILINE - PROTONIC ACID DOPING TO THE METALLIC REGIME
MACDIARMID, AG
CHIANG, JC
HUANG, WS
HUMPHREY, BD
SOMASIRI, NLD
[J]. MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1985, 125 (1-4): : 309 - 318
[17] MACDIARMID AG, 1986, IN PRESS CONDUCTING
[18] X-RAY-DIFFRACTION PATTERN AND MODELS OF LIQUID BENZENE
NARTEN, AH
[J]. JOURNAL OF CHEMICAL PHYSICS, 1977, 67 (05) : 2102 - 2108
[19] ATOM PAIR POTENTIALS OF LIQUID-NITROGEN FROM DIFFRACTION DATA
NARTEN, AH
JOHNSON, E
HABENSCHUSS, A
[J]. JOURNAL OF CHEMICAL PHYSICS, 1980, 73 (03) : 1248 - 1255
[20] NARTEN AH, 1972, WATER COMPREHENSIVE, V1, P314

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