COMPLEXES OF NICKEL(II) AND PALLADIUM(II) WITH THIOBENZAMIDE

被引：10

作者：

AARTS, AJ ^{[1
]}

DESSEYN, HO ^{[1
]}

HERMAN, MA ^{[1
]}

机构：

[1] RIJKSUNIV CENT,ANORGAN SCHEIKUNDE LAB,B-2020 ANTWERPEN,BELGIUM

来源：

TRANSITION METAL CHEMISTRY | 1979年 / 4卷 / 01期

关键词：

D O I：

10.1007/BF00941017

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The electronic and vibrational spectra of NiII and PdII complexes with thiobenzamide, L, are discussed. L acts as a sulphur donor ligand. The PdII compounds and (NiL4)(ClO4)2 are square planar. PdL2Cl2 has a cis-structure, while PdL2X2 (X=Br or I) is trans; NiL4Cl2 is trans-octahedral. The i.r. bands due to ν(M.S) and ν(MX) have been assigned. The influence of the anions on the properties of the complexes, both in solution and in the solid state, is discussed. © 1979 Verlag Chemie, GmbH.

引用

页码：46 / 48

页数：3

共 24 条

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