THE STUDY OF CATALYST EFFECTS ON THE COMPLEXATION OF ARENES WITH CR(CO)6 - AN OVERVIEW

被引：25

作者：

HUDECEK, M ^{[1
]}

GAJDA, V ^{[1
]}

TOMA, S ^{[1
]}

机构：

[1] COMENIUS UNIV BRATISLAVA,DEPT ORGAN CHEM,CS-84215 BRATISLAVA,SLOVAKIA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 413卷 / 1-3期

关键词：

D O I：

10.1016/0022-328X(91)80046-M

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New results from our thorough investigation of different catalystic effects on the rate and yields of complexation of arenes with Cr(CO) are presented with a short review of the subject. With decalin as solvent the following substances were found to be the best catalysts: butyl acetate, ethyl formate, and dimethyl succinate. Butyl acetate proved to be the catalyst also in di-n-butyl ether. Special attention was paid to the complexation of naphthalene, and chlorobenzene. Some unsuccessful attempts at asymmetric induction of complexation are also described.

引用

页码：155 / 160

页数：6

共 15 条

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