NUCLEOPHILIC VINYLIC SUBSTITUTIONS OF (Z)-(BETA-(PHENYLSULFONYL)ALKENYL)IODONIUM TETRAFLUOROBORATES WITH TETRABUTYLAMMONIUM HALIDES - RETENTION OF CONFIGURATION

被引：40

作者：

OCHIAI, M

OSHIMA, K

MASAKI, Y

机构：

[1] Gifu Pharmaceutical University, Gifu, 502

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 52期

关键词：

D O I：

10.1016/0040-4039(91)80572-N

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Nucleophilic vinylic substitutions of (Z)-(beta-(phenylsulfonyl)alkenyl)-phenyliodonium tetrafluoroborates 1 with tetrabutylammonium halides (Cl, Br, and I) proceed with exclusive retention of configuration at room temperature and afford (Z)-beta-(phenylsulfonyl)vinyl halides 2 in high yields.

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页码：7711 / 7714

页数：4

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