FERROELECTRIC LIQUID-CRYSTALLINE SIDE-GROUP POLYMERS - SPACER LENGTH VARIATION AND COMPARISON WITH THE MONOMERS

被引：14

作者：

KUHNPAST, K

SPRINGER, J

SCHEROWSKY, G

GIESSELMANN, F

ZUGENMAIER, P

机构：

[1] TECH UNIV BERLIN,FACHGEBIET MAKROMOLEK CHEM,INST TECH CHEM,W-1000 BERLIN 12,GERMANY

[2] TECH UNIV BERLIN,INST ORGAN CHEM,W-1000 BERLIN 12,GERMANY

[3] TECH UNIV CLAUSTHAL,INST PHYS CHEM,W-3392 CLAUSTHAL ZELLERFE,GERMANY

来源：

LIQUID CRYSTALS | 1993年 / 14卷 / 03期

关键词：

D O I：

10.1080/02678299308027763

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The phase behaviour and the ferroelectric properties of liquid-crystalline side group polyacrylates containing an (R)-4''-(1-methylheptyloxy)-4'-biphenylyloxycarbonyl-4-phenoxy moiety are compared with the properties of their monomers. A S(C)* phase polymorphism including monolayer and bilayer structures was found for the polymers. Some of the S(C)* subphases, consisting of smectic mono- or bi-layers, do not exhibit ferroelectric properties. These unusual properties do not exist for the corresponding monomeric acrylates. Therefore, one has to take into account that the polymer chain exerts a strong influence on the phase behaviour and the ferroelectric properties.

引用

页码：861 / 869

页数：9

共 16 条

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