COMPLETE H-1-RESONANCE AND C-13-RESONANCE ASSIGNMENTS FOR D-MANNOOLIGOSACCHARIDES OF THE BETA-D-(1-]2)-LINKED SERIES RELEASED FROM THE PHOSPHOPEPTIDOMANNAN OF CANDIDA-ALBICANS VW-32 (SEROTYPE-A)

被引：20

作者：

FAILLE, C

WIERUSZESKI, JM

MICHALSKI, JC

POULAIN, D

STRECKER, G

机构：

[1] UNIV SCI & TECH LILLE FLANDRES ARTOIS,CHIM BIOL LAB,F-59650 VILLENEUVE DASCQ,FRANCE

[2] UNIV SCI & TECH LILLE FLANDRES ARTOIS,CNRS,UNITE MIXTE RECH,F-59650 VILLENEUVE DASCQ,FRANCE

[3] INSERM,U42,F-59650 VILLENEUVE DASCQ,FRANCE

来源：

CARBOHYDRATE RESEARCH | 1992年 / 236卷

关键词：

D O I：

10.1016/0008-6215(92)85004-J

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

D-Mannooligosaccharides (dp 1 to > 17) were released by mild acid hydrolysis from the phosphopeptidomannan of a Candida albicans strain of A serotype (VW.32). Among these, mannooligosaccharides ranging from bi- to hepta-ose, which were obtained in appreciable amounts, were structurally investigated and found to belong to the beta-D-(1 --> 2)-linked series. The occurrence of such compounds has already been reported in other Candida albicans strains. The complete H-1- and C-13-resonance assignments for manno-tri- to manno-hepta-ose are reported and general rules applicable for the 1NMR spectrum analysis of linear mannooligosaccharide of the general structure, beta-D-Manp-(1 --> 2)-beta-D-Manp-(1 --> 2)]n-beta-D-Manp are proposed.

引用

页码：17 / 27

页数：11

共 9 条

[1]

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[2] H-1 - NMR-SPECTROSCOPY OF MANNO-OLIGOSACCHARIDES OF THE BETA-1,2-LINKED SERIES RELEASED FROM THE PHOSPHOPEPTIDOMANNAN OF CANDIDA-ALBICANS VW - 32 (SEROTYPE-A) [J].