A THEORY FOR THE TEMPERATURE-DEPENDENCE OF HOLE-BURNED SPECTRA

被引：76

作者：

HAYES, JM ^{[1
]}

LYLE, PA ^{[1
]}

SMALL, GJ ^{[1
]}

机构：

[1] IOWA STATE UNIV SCI & TECHNOL,US DOE,AMES LAB,AMES,IA 50011

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1994年 / 98卷 / 30期

关键词：

D O I：

10.1021/j100081a017

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A theory is presented for the temperature dependence of the absorption and hole-burned spectra of chromophores imbedded in solids characterized by structural heterogeneity. The theory is applicable for arbitrarily strong linear electron-phonon coupling and describes the overall hole profile which consists of the zero-phonon hole and its associated phonon sideband hole structure. A novel and convenient form for the thermally averaged Franck-Condon factors is employed. Illustrative calculations are presented which pertain to the temperature dependence of the absorption band of the primary electron donor of the photosynthetic bacterial reaction center and the design of high-temperature hole-burning materials for high-density frequency domain optical storage.

引用

页码：7337 / 7341

页数：5