A NEW APPROACH TO INDOLE ALKALOIDS VIA INDOLE CHROMIUM COMPLEXES

被引：31

作者：

SEMMELHACK, MF

KNOCHEL, P

SINGLETON, T

机构：

[1] Department of Chemistry, Princeton University, Princeton

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 32期

关键词：

D O I：

10.1016/S0040-4039(00)60673-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The activating effect of pi complexation of a Cr(CO)3 unit allows selective nucleophilic substitution in indoles such as tryptophan derivatives and provides intermediates for the synthesis of clavicipitic acid and related indole natural products.

引用

页码：5051 / 5054

页数：4

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