OXYGEN ACTIVATION ON NICKEL(II)TETRAHYDROSALEN COMPLEXES WITH THE FORMATION OF NICKEL(II)DIHYDROSALEN COMPLEXES

被引：54

作者：

BOTTCHER, A

ELIAS, H

MULLER, L

PAULUS, H

机构：

[1] TH DARMSTADT,EDUARD ZINTL INST,HOCHSCHULSTR 10,W-6100 DARMSTADT,GERMANY

[2] TH DARMSTADT,FACHBEREICH MAT WISSENSCH,W-6100 DARMSTADT,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1992年 / 31卷 / 05期

关键词：

D O I：

10.1002/anie.199206231

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The oxidative dehydrogenation of only one C-N bond in the [Ni(tetrahydrosalen)] complex 1 surprisingly affords the corresponding [Ni(dihydrosalen)] complex. This reaction is thus a rare example of the activation of oxygen by nickel complexes. The Ni atom in 1 has an almost square-planar coordination geometry, and the two benzene rings are bent slightly upwards and downwards relative to the NiO2N2 plane.

引用

页码：623 / 625

页数：3

共 16 条

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