TRIS(TRIMETHYLSILYL)SILANE AND DIPHENYLSILANE IN THE RADICAL CHAIN DIDEOXYGENATION OF 1,6-ANHYDRO-D-GLUCOSE - A COMPARATIVE-STUDY

被引:22
作者
BARTON, DHR [1 ]
JANG, DO [1 ]
JASZBERENYI, JC [1 ]
机构
[1] TEXAS A&M UNIV SYST,DEPT CHEM,COLL STN,TX 77843
关键词
D O I
10.1016/S0040-4039(00)61003-1
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The 2,4-bis-thionocarbonate 3 of 1,6-anhydro-D-glucose 1 can be transformed to the corresponding dideoxy compounds 5 with diphenylsilane 7 as well as with tris(trimethylsilyl)silane 4 in a radical chain reaction.
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页码:6629 / 6632
页数:4
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