3,3,3-TRIFLUORO-1-NITROPROPENE AS A NOVEL TRIFLUOROMETHYL-CONTAINING BUILDING-BLOCK

被引：40

作者：

IWATA, S ^{[1
]}

ISHIGURO, Y ^{[1
]}

UTSUGI, M ^{[1
]}

MITSUHASHI, K ^{[1
]}

TANAKA, K ^{[1
]}

机构：

[1] SEIKEI UNIV, FAC ENGN, MUSASHINO, TOKYO 180, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1993年 / 66卷 / 08期

关键词：

D O I：

10.1246/bcsj.66.2432

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Additions of various carbanion nucleophiles to 3,3,3-trifluoro-1-nitropropene (1) proceeded regiospecifically at the C-2 position of 1 to give the corresponding adducts. The nitro group of the adducts, derived from the reactions with acetylacetone and ethyl acetoacetate, was reduced to the corresponding amines, which were cyclized in situ to the 3-(trifluoromethyl)pyrrole derivatives.

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页码：2432 / 2435

页数：4

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