STEREOSELECTIVE ALLYLATION OF BETA-HYDROXY-ALPHA,BETA-ENONES AND BETA-AMINO-ALPHA,BETA-ENONES WITH ALLYLTRIFLUOROSILANE TRIETHYLAMINE SYSTEMS

被引:11
作者
KIRA, M
SATO, K
SEKIMOTO, K
GEWALD, R
SAKURAI, H
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D O I
10.1246/cl.1995.281
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Reactions of allyltrifluorosilanes with beta-functional-alpha,beta-enones such as o-hydroxy- and o-aminophenyl ketones and 1,3-diketones in the presence of triethylamine yielded the corresponding tertiary homoallyl alcohols in regiospecific and highly diastereoselective manner.
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页码:281 / 282
页数:2
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