TRANSITION METAL-METHYLENE COMPLEXES .8. MASS-SPECTROMETRIC ANALYSIS OF MU-METHYLENE COMPLEXES OF COBALT, RHODIUM, MANGANESE AND IRON

被引：19

作者：

MAYER, KK

HERRMANN, WA

机构：

[1] Fachbereich Chemie und Pharmazie der Universität Regensburg, D-8400 Regensburg 1

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 182卷 / 03期

关键词：

D O I：

10.1016/S0022-328X(00)84819-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The electron impact induced decomposition pathways of several μ-methylene complexes of Co, Rh, Mn, and Fe were elucidated by high resolution measurements, analysis of metastable transitions, and 2H-labelling. The fragmentation patterns are discussed with regard to the nature of the different central atoms and methylene ligands, and compared With those of terminal carbene complexes. © 1979.

引用

页码：361 / 374

页数：14

共 51 条

[31] COMPLEX CHEMISTRY OF REACTIVE ORGANIC COMPOUNDS .9. INSERTION OF METHYLENE IN MANGANESE COMPLEXES [J].