HIGH-SPIN 5-COORDINATE COBALT(2) COMPLEXES

被引：50

作者：

DORI, Z

GRAY, HB

机构：

[1] Department of Chemistry, Columbia University

[2] Gates and Crellin Laboratories of Chemistry, California Institute of Technology, Pasadena

来源：

INORGANIC CHEMISTRY | 1968年 / 7卷 / 05期

关键词：

D O I：

10.1021/ic50063a010

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Preparation and characterization of Co(Et4dien)X2 (Et4dien = HN[CH2CH2N(C2H5)2]2; X = Cl, Br, I, N3, NCS) complexes are reported. Spectral and magnetic properties show that the complexes are high spin and five-coordinate in the solid state. Based on a ligand field model, an interpretation of the observed electronic spectra and magnetic moments is presented. © 1968, American Chemical Society. All rights reserved.

引用

页码：889 / &

共 16 条

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