ASYMMETRIC SILYLPHOSPHITE ESTERS - SYNTHESIS AND REACTIVITY OF (RAC-O,O-BINAPHTHOLATO)POSIR3 (R3=PH3,(T)BUME2,ET3)

被引：36

作者：

GREENE, N ^{[1
]}

KEE, TP ^{[1
]}

机构：

[1] UNIV LEEDS, SCH CHEM, LEEDS LS2 9JT, W YORKSHIRE, ENGLAND

来源：

SYNTHETIC COMMUNICATIONS | 1993年 / 23卷 / 12期

关键词：

D O I：

10.1080/00397919308011262

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The new, silylphosphite compounds, (rac-O,O-binaphtholato)POSiR3 (R3 = Ph3, tBuMe2, Et3) have been synthesised by the reactions of (rac-O,O-binaphtholato)PCl and R3SiOH. The abilities of these silylphosphite esters to act as phosphonylating agents towards benzaldehyde have been investigated.

引用

页码：1651 / 1657

页数：7

共 6 条

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