A NEW ALKOXYIODINATION AND NITRATOIODINATION OF ALPHA,BETA-UNSATURATED KETONE AND ESTER USING IODINE-CERIUM(IV) AMMONIUM-NITRATE

被引：22

作者：

HORIUCHI, CA

OCHIAI, K

FUKUNISHI, H

机构：

来源：

CHEMISTRY LETTERS | 1994年 / 02期

关键词：

D O I：

10.1246/cl.1994.185

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of alpha,beta-unsaturated ketones and electron-deficent unsaturated esters with iodine-cerium(IV) ammonium nitrate in alcohols (methanol, ethanol, or l-propanol) under 0 degrees C-reflux gave the corresponding beta-alkoxy-alpha-iodoketones and esters in good yields. In the case of acetonitrile and acetonitrile-water, beta-nitrato- and beta-hydroxy-alpha-iodo compounds were obtained,;respectively.

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页码：185 / 188

页数：4

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