STRUCTURE OF THE TRIVALENT MOLYBDENUM METAPHOSPHATE MO(PO3)3

被引：27

作者：

WATSON, IM ^{[1
]}

BOREL, MM ^{[1
]}

CHARDON, J ^{[1
]}

LECLAIRE, A ^{[1
]}

机构：

[1] UNIV CAEN,ISMRA,CNRS,CRISMAT LAB,F-14050 CAEN,FRANCE

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 1994年 / 111卷 / 02期

关键词：

D O I：

10.1006/jssc.1994.1225

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Crystals of the molybdenum(III) metaphosphate Mo(PO3)3 were grown by chemical vapor transport with iodine (1173 K --> 1073 K). The structure was determined by single crystal X-ray diffraction. Mo(PO3)3 crystallizes in the monoclinic space group Ia, with a = 10.819(1) angstrom, b = 19.515(3) angstrom, c = 9.609(1) angstrom, beta = 97.74(1)degrees, and Z = 12. Mo(PO3)3, and has a structure consisting of infinite chains of corner-sharing PO4 tetrahedra running along [001], bridged by isolated MoO6 octahedra. The octahedra are regular, with an average Mo-O distance of 2.084 angstrom. The structure can also be viewed as containing infinite MoP3O14 chains along [102], which are linked so as to define small tunnels running in the same direction. (C) 1994 Academic Press, Inc.

引用

页码：253 / 256

页数：4

共 13 条

[1] STRUCTURE OF KMOP2O7, A MOLYBDENUM PYROPHOSPHATE CONTAINING ISOLATED MO3+ CATIONS [J].