ELECTROCHEMICAL OXIDATIONS .4. ELECTROCHEMICAL INVESTIGATIONS INTO THE BEHAVIOR OF 2,6-DI-TERT-BUTYL-4-(4-DIMETHYLAMINOPHENYL)-PHENOL .1. PHENOL AND THE SPECIES DERIVED FROM IT - PHENOXY RADICAL, PHENOLATE ANION AND PHENOXENIUM CATION

被引：55

作者：

SPEISER, B

RIEKER, A

机构：

[1] Institut für Organische Chemie, Universität Tübingen, Auf der Morgenstelle 18

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1979年 / 102卷 / 03期

关键词：

D O I：

10.1016/S0022-0728(79)80465-9

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The anodic oxidation of 2,6-di-tert-butyl-4-(4-dimethylaminophenyl)phenol (IIa) was investigated by cyclic voltammetry. The stable products resulting from the oxidation are phenoxenium cation (IId) (which itself is reduced in two one-electron steps to the phenolate anion (IIc) via the phenoxy radical, IIb) and the protonated phenol (III) (which is oxidized to (IId) in a second peak at higher potential). A mechanism for the electrochemical oxidation of phenol (IIa) is suggested. © 1979 Elsevier Sequoia S.A."

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页码：373 / 395

页数：23

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