PALLADIUM-CATALYZED HYDROGENATION OF ALPHA,BETA-UNSATURATED SULFONES AND PHOSPHONATES

被引：21

作者：

CHO, IS ^{[1
]}

ALPER, H ^{[1
]}

机构：

[1] UNIV OTTAWA,DEPT CHEM,OTTAWA K1N 6N5,ON,CANADA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1994年 / 59卷 / 15期

关键词：

D O I：

10.1021/jo00094a001

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The binuclear palladium complex, [(Bu(2)(t)PH)-PdPBu(2)(t)](2), when treated with oxygen, catalyzes the hydrogenation of the double bond of alpha,beta-unsaturated sulfones and phosphonates in THF at room temperature and 1 atm of hydrogen pressure. Saturated sulfones and phosphonates were isolated in 49-93% yields.

引用

页码：4027 / 4028

页数：2

共 15 条

[1] EXPLORATION OF N-PHOSPHONOALKYL-SPACED, N-PHOSPHONOALKENYL-SPACED, AND N-(PHOSPHONOALKYL)PHENYL-SPACED ALPHA-AMINO-ACIDS AS COMPETITIVE N-METHYL-D-ASPARTIC ACID ANTAGONISTS
BIGGE, CF
JOHNSON, G
ORTWINE, DF
DRUMMOND, JT
RETZ, DM
BRAHCE, LJ
COUGHENOUR, LL
MARCOUX, FW
PROBERT, AW
[J]. JOURNAL OF MEDICINAL CHEMISTRY, 1992, 35 (08) : 1371 - 1384
[2] EXPLORATION OF PHENYL-SPACED 2-AMINO-(5-9)-PHOSPHONOALKANOIC ACIDS AS COMPETITIVE N-METHYL-D-ASPARTIC ACID ANTAGONISTS
BIGGE, CF
DRUMMOND, JT
JOHNSON, G
MALONE, T
PROBERT, AW
MARCOUX, FW
COUGHENOUR, LL
BRAHCE, LJ
[J]. JOURNAL OF MEDICINAL CHEMISTRY, 1989, 32 (07) : 1580 - 1590
[3] HIGHLY SELECTIVE ADENOSINE-A2 RECEPTOR AGONISTS IN A SERIES OF N-ALKYLATED 2-AMINOADENOSINES
FRANCIS, JE
WEBB, RL
GHAI, GR
HUTCHISON, AJ
MOSKAL, MA
DEJESUS, R
YOKOYAMA, R
ROVINSKI, SL
CONTARDO, N
DOTSON, R
BARCLAY, B
STONE, GA
JARVIS, MF
[J]. JOURNAL OF MEDICINAL CHEMISTRY, 1991, 34 (08) : 2570 - 2579
[4] GROUP-6 ANIONIC MU-HYDRIDE COMPLEXES [HCR2(CO)10]-, [HMO2(CO)10]-, [HW2(CO)10]- - NEW CATALYSTS FOR HYDROGENATION AND HYDROSILYLATION
FUCHIKAMI, T
UBUKATA, Y
TANAKA, Y
[J]. TETRAHEDRON LETTERS, 1991, 32 (09) : 1199 - 1202
[5] STEREOSELECTIVE SYNTHESIS OF VINYLPHOSPHONATE
HIRAO, T
MASUNAGA, T
OHSHIRO, Y
AGAWA, T
[J]. TETRAHEDRON LETTERS, 1980, 21 (37) : 3595 - 3598
[6] REACTIONS OF PARA-TOLUENESULFONYL CHLORIDE WITH STYRENES CATALYZED BY DICHLOROTRIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II)
KAMIGATA, N
SAWADA, H
KOBAYASHI, M
[J]. CHEMISTRY LETTERS, 1979, (02) : 159 - 162
[7] Keinan E., 1991, COMPREHENSIVE ORGANI, VIII, P523
[8] SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF A NEW PALLADIUM CATALYST PRECURSOR CONTAINING AN ETA-2-PHOSPHINATE
LEONI, P
MARCHETTI, F
PASQUALI, M
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1993, 451 (1-2) : C25 - C27
[9] A SIMPLE SYNTHESIS AND CRYSTAL-STRUCTURE OF THE DINUCLEAR DIPHOSPHIDO-BRIDGED PALLADIUM(I) COMPLEX [PD(P(TERT-BU)2H)(MU-P(TERT-BU)2)]2
LEONI, P
SOMMOVIGO, M
PASQUALI, M
SABATINO, P
BRAGA, D
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1992, 423 (02) : 263 - 270
[10] THE TOTAL SYNTHESIS OF THE CLERODANE DITERPENE INSECT ANTIFEEDANT AJUGARIN-I
LEY, SV
SIMPKINS, NS
WHITTLE, AJ
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1983, (09) : 503 - 505

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