The origin of the quadrupole splitting in the mossbauer spectra of some organotin halide complexes

被引：18

作者：

Parish, R. V. ^{[1
]}

Johnson, C. E. ^{[2
]}

机构：

[1] UMIST, Dept Chem, Manchester M60 1QD, Lancs, England

[2] AERE, Div Mat Phys, Didcot, Berkshire, England

来源：

CHEMICAL PHYSICS LETTERS | 1970年 / 6卷 / 03期

关键词：

D O I：

10.1016/0009-2614(70)80229-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Mossbauer spectra of some organotin(IV) chloride complexes, measured in an applied magnetic field. show that the quadrupole interaction (1/2e(2)qQ) is positive when the organic groups occupy axial positions and negative when they are equatorial: this implies that the electric field gradient arises primarily in the valence-shell of the tin atom.

引用

页码：239 / 240

页数：2