STRUCTURES AND IONIZATION ENERGIES OF SANDWICH CLUSTERS (V-N(BENZENE)(M))

被引：182

作者：

HOSHINO, K ^{[1
]}

KURIKAWA, T ^{[1
]}

TAKEDA, H ^{[1
]}

NAKAJIMA, A ^{[1
]}

KAYA, K ^{[1
]}

机构：

[1] KEIO UNIV,FAC SCI & TECHNOL,DEPT CHEM,KOHOKU KU,YOKOHAMA,KANAGAWA 223,JAPAN

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1995年 / 99卷 / 10期

关键词：

D O I：

10.1021/j100010a013

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Metal-molecule clusters V-n(benzene)(m) were synthesized by the reaction of laser-vaporized vanadium atoms with benzene vapor. The clusters exhibit magic number behavior at m = n - 1, n, and n + 1 (n = 1-5), which is explicable in terms of the multiple decker sandwich structure for these stable clusters. The ionization energies of these sandwich clusters decrease significantly with increasing cluster size.

引用

页码：3053 / 3055

页数：3

共 21 条

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