REACTIONS OF BENZENE CLUSTERS WITH METAL-IONS AS STUDIED BY THE LASER ABLATION MOLECULAR-BEAM METHOD - OBSERVATION OF CLUSTERED COMPLEX-IONS M(C6H6)N+ (N GREATER-THAN-OR-EQUAL-TO 2) AND FRAGMENT-COMPLEX IONS M(C6H6)(CXHY)+ WITH X LESS-THAN-OR-EQUAL-TO 6 AND Y LESS-THAN-OR-EQUAL-TO 4

被引：63

作者：

HIGASHIDE, H ^{[1
]}

KAYA, T ^{[1
]}

KOBAYASHI, M ^{[1
]}

SHINOHARA, H ^{[1
]}

SATO, H ^{[1
]}

机构：

[1] MIE UNIV,FAC ENGN,CHEM DEPT RESOURCES,TSU,MIE 514,JAPAN

来源：

CHEMICAL PHYSICS LETTERS | 1990年 / 171卷 / 04期

关键词：

D O I：

10.1016/0009-2614(90)85367-L

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Ion-molecule reactions of small benzene clusters with metal ions (M+) are studied for the first time by the laser ablation-molecular beam method. The clustered complex ions M(C6H6)+n (n≥2) are formed and stabilized as a result of the evaporation of benzene molecule(s). The reactions of Y+, Nb+ and Ta+ with benzene clusters cause extensive molecular elimination to form the fragment complex ions M(C6H6)(CxHy)+ (X=2, 4, 6; Y=0,2,4). © 1990.

引用

页码：297 / 302

页数：6

共 25 条

[1] 260-NM ABSORPTION-SPECTRUM OF BENZENE - RE-MEASURED BAND POSITIONS AND REFINED ASSIGNMENTS [J].

ATKINSON, GH ;

PARMENTER, CS .

JOURNAL OF MOLECULAR SPECTROSCOPY, 1978, 73 (01) :20-30

[2] DISSOCIATION DYNAMICS OF INTERNAL ENERGY SELECTED C6H6+ [J].

BAER, T ;

WILLETT, GD ;

SMITH, D ;

PHILLIPS, JS .

JOURNAL OF CHEMICAL PHYSICS, 1979, 70 (09) :4076-4085

[3]

Baer T., 1986, ADV CHEM PHYS, V64, P111

[4] STRAHLEN AUS KONDENSIERTEM WASSERSTOFF, KONDENSIERTEM HELIUM UND KONDENSIERTEM STICKSTOFF IM HOCHVAKUUM [J].

BECKER, EW ;

LOHSE, P ;

KLINGELHOFER, R .

ZEITSCHRIFT FUR NATURFORSCHUNG PART A-ASTROPHYSIK PHYSIK UND PHYSIKALISCHE CHEMIE, 1962, A 17 (05) :432-&

[5] METAL-COMPLEXES OF SMALL CYCLOALKYNES AND ARYNES [J].

BENNETT, MA ;

SCHWEMLEIN, HP .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1989, 28 (10) :1296-1320

[6] DETERMINATION OF CLUSTER BINDING-ENERGY FROM EVAPORATIVE LIFETIME AND AVERAGE KINETIC-ENERGY RELEASE - APPLICATION TO (CO2)N+ AND ARN+ CLUSTERS [J].

ENGELKING, PC .

JOURNAL OF CHEMICAL PHYSICS, 1987, 87 (02) :936-940

[7]

FREISER BS, 1986, J AM CHEM SOC, V108, P5086

[8]

Hagena O. F., 1974, MOL BEAMS LOW DENSIT, P93

[9] REACTIONS OF METAL-IONS AND BENZENE AS STUDIED BY THE LASER ABLATION-MOLECULAR BEAM METHOD - PRESSURE AND KINETIC-ENERGY DEPENDENCES OF ION-MOLECULE REACTIONS [J].

HIGASHIDE, H ;

OKA, T ;

KASATANI, K ;

SHINOHARA, H ;

SATO, H .

CHEMICAL PHYSICS LETTERS, 1989, 163 (06) :485-489

[10] CLUSTERS OF ORGANIC-MOLECULES IN A SUPERSONIC JET EXPANSION [J].

JONKMAN, HT ;

EVEN, U ;

KOMMANDEUR, J .

JOURNAL OF PHYSICAL CHEMISTRY, 1985, 89 (20) :4240-4243

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