REACTIONS OF BENZENE CLUSTERS WITH METAL-IONS AS STUDIED BY THE LASER ABLATION MOLECULAR-BEAM METHOD - OBSERVATION OF CLUSTERED COMPLEX-IONS M(C6H6)N+ (N GREATER-THAN-OR-EQUAL-TO 2) AND FRAGMENT-COMPLEX IONS M(C6H6)(CXHY)+ WITH X LESS-THAN-OR-EQUAL-TO 6 AND Y LESS-THAN-OR-EQUAL-TO 4

被引：63

作者：

HIGASHIDE, H ^{[1
]}

KAYA, T ^{[1
]}

KOBAYASHI, M ^{[1
]}

SHINOHARA, H ^{[1
]}

SATO, H ^{[1
]}

机构：

[1] MIE UNIV,FAC ENGN,CHEM DEPT RESOURCES,TSU,MIE 514,JAPAN

来源：

CHEMICAL PHYSICS LETTERS | 1990年 / 171卷 / 04期

关键词：

D O I：

10.1016/0009-2614(90)85367-L

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Ion-molecule reactions of small benzene clusters with metal ions (M+) are studied for the first time by the laser ablation-molecular beam method. The clustered complex ions M(C6H6)+n (n≥2) are formed and stabilized as a result of the evaporation of benzene molecule(s). The reactions of Y+, Nb+ and Ta+ with benzene clusters cause extensive molecular elimination to form the fragment complex ions M(C6H6)(CxHy)+ (X=2, 4, 6; Y=0,2,4). © 1990.

引用

页码：297 / 302

页数：6

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